01/By surface
each with its own count, at equal weight
Hard
1-0
S. leads 1-0 in 1 meeting on hard
Clay
1-0
S. leads 1-0 in 1 meeting on clay
Grass
1-0
S. leads 1-0 in 1 meeting on grass
02/Every meeting
3 rows, newest first
| Date | Tournament | Surface | Round | Winner | Score, winner first | Ranks, S. first |
|---|---|---|---|---|---|---|
| Jul 5, 2016 | WimbledonGrand Slam | grass | quarterfinal | Williams S. | 6-4, 6-4 | 1 v 23 |
| May 12, 2015 | Internazionali BNL d'ItaliaPremier | clay | 2nd round | Williams S. | 6-1, 6-3 | 1 v 39 |
| Jan 5, 2013 | Brisbane InternationalInternational | hard | final | Williams S. | 6-2, 6-1 | 3 v 36 |
A record, never a share of meetings. Main-draw singles since 2013; a meeting ended by retirement is counted with the sets that were played and marked; a walkover is listed and counted in neither column. Williams S. and Pavlyuchenkova A. each carry the table against every opponent faced.